HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formaldehyde → 4,4-Di(hydroxymethyl)bicyclo(2.2.1)heptene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formaldehyde | HCID 712 | — |
| Reactant | Bicyclo(2.2.1)hept-5-ene-2-carboxaldehyde | HCID 95117 | — |
| Product | 4,4-Di(hydroxymethyl)bicyclo(2.2.1)heptene | HCID 110917 | — |
Reaction Steps
The synthesis of this chemical compound is depicted in Table I. The synthesis consists of the reaction of cyclopentene with acrolein to produce 5-norbornene-2-al. Reaction of 5-norbornene-2-al with formaldehyde results in the formation of 5-norbornene-2,2-dimethanol. Mild oxidation of the latter compound with dibutylstannic oxide yields the 3,9-bis(5'-norbornene-2'yl)-1,5,7,11-tetraoxaspiro[5.5]undecane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04515912 |
| Source dataset | uspto-grants-1985_05 |
| ORD ID | ord-28176567ee1b4f57bad6f55744d701ad |
| Source note | uspto-grants-1985_05 |