Cyclohexylamine → HCID 178438299, compound

HRID 462562Notes

Reaction equation

HRID 462562 reaction equation
[CH2:1]([C:4]12[CH2:10][CH:7]([CH:8]=[CH:9]1)[CH:6]1[C:11]([O:13][C:14](=[O:15])[CH:5]21)=[O:12])[CH:2]=[CH2:3].[CH:16]1([NH2:22])[CH2:21][CH2:20][CH2:19][CH2:18][CH2:17]1>>[CH:16]1([N:22]=[C:14]([CH:5]2[CH:6]([C:11]([OH:13])=[O:12])[CH:7]3[CH2:10][C:4]2([CH2:1][CH:2]=[CH2:3])[CH:9]=[CH:8]3)[OH:15])[CH2:21][CH2:20][CH2:19][CH2:18][CH2:17]1

Participants

3

Reactant 2

HCID 7965CyclohexylamineHCID 54206110Allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride

Product 1

HCID 178438299HCID 178438299, compound

Procedure

102 g of allyl-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid anhydride and 100 g of cyclohexylamine are heated to 137° C. under 4,000 Pa. 59 ml of water and excess cyclohexylamine are distilled off. Distillation of the residue at 162°-163° C. under 10.7 Pa gives 87.6 g (62% of theory) of an oil of nD20 1.5296 and η25 72.8 Pa.s.

Workup

  1. distillation59 ml of water and excess cyclohexylamine are distilled off
  2. distillationDistillation of the residue at 162°-163° C. under 10.7 Pa
  3. customgives 87.6 g (62% of theory) of an oil of nD20 1.5296 and η25 72.8 Pa.s

Sources & evidence

ORD record
ord-e9678ef018a743c093ed6feaf77b678e
Source dataset
uspto-grants-1985_05
Patent number
US04515962

Reaction notes

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