3,4-Dichlorobenzenethiol → 6-[2-(3,4-Dichloro-phenylmercapto)-ethoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

HRID 463107Notes

Reaction equation

HRID 463107 reaction equation
Cl[CH2:2][CH2:3][O:4][C:5]1[CH:6]=[CH:7][C:8]2[NH:13][C:12](=[O:14])[O:11][C:10]([CH3:16])([CH3:15])[C:9]=2[CH:17]=1.[Cl:18][C:19]1[CH:20]=[C:21]([SH:26])[CH:22]=[CH:23][C:24]=1[Cl:25]>>[Cl:18][C:19]1[CH:20]=[C:21]([S:26][CH2:2][CH2:3][O:4][C:5]2[CH:6]=[CH:7][C:8]3[NH:13][C:12](=[O:14])[O:11][C:10]([CH3:16])([CH3:15])[C:9]=3[CH:17]=2)[CH:22]=[CH:23][C:24]=1[Cl:25]

Participants

3

Reactant 2

HCID 799643,4-DichlorobenzenethiolHCID 202818476-(2-Chloroethoxy)-4,4-dimethyl-1,4-dihydro-2H-3,1-benzoxazin-2-one

Product 1

HCID 132605396-[2-(3,4-Dichloro-phenylmercapto)-ethoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Procedure

Prepared analogously to Example 1 from 6-(2-chloroethoxy)-4,4-dimethyl-4H-3,1-benzoxazin-2-one and 3,4-dichloro-thiophenol.

Sources & evidence

ORD record
ord-97419d3bc03340dabfb3ead693978671
Source dataset
uspto-grants-1985_05
Patent number
US04518597

Reaction notes

Loading…