Sulfur dichloride → HCID 20264381, compound

HRID 463614Notes

Reaction equation

HRID 463614 reaction equation
[Cl:1][C:2]1[C:3]([O:12][C:13]2[CH:22]=[CH:21][C:16]3=[N+:17]([O-])[O:18][N:19]=[C:15]3[CH:14]=2)=[N:4][CH:5]=[C:6]([C:8]([F:11])([F:10])[F:9])[CH:7]=1.[S:23](Cl)Cl>>[Cl:1][C:2]1[C:3]([O:12][C:13]2[CH:22]=[CH:21][C:16]3=[N:17][S:23][N:19]=[C:15]3[CH:14]=2)=[N:4][CH:5]=[C:6]([C:8]([F:11])([F:10])[F:9])[CH:7]=1.[Cl:1][C:2]1[C:3]([O:12][C:13]2[CH:22]=[CH:21][C:16]3=[N+:17]([O-:18])[S:23][N:19]=[C:15]3[CH:14]=2)=[N:4][CH:5]=[C:6]([C:8]([F:11])([F:10])[F:9])[CH:7]=1

Participants

4

Reactant 2

HCID 25353Sulfur dichlorideHCID 53687562HCID 53687562, compound

Product 2

HCID 20264381HCID 20264381, compoundHCID 54080168HCID 54080168, compound

Procedure

Likewise, 5-(3-chloro-5-trifluoromethyl-2-pyridyloxy)benzo-2,1,3-oxadiazole N-oxide is reduced, and the resulting dioxime is reacted with sulfur dichloride to give 5-(3-chloro-5-trifluoromethyl-2-pyridyloxy)benzo-2,1,3-thiadiazole and 5-(3-chloro-5-trifluoromethyl-2-pyridyloxy)benzo-2,1,3-thiadiazole N-oxide.

Sources & evidence

ORD record
ord-3f338a2b56d946668ace2dc46cf6bf41
Source dataset
uspto-grants-1985_10
Patent number
US04544400

Reaction notes

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