HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrazine → N'-[(4-cyanophenyl)methylidene]benzenesulfonohydrazide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrazine | HCID 9321 | — |
| Reactant | Benzenesulfonyl hydrazide | HCID 65723 | — |
| Reactant | 4-Cyanobenzaldehyde | HCID 66042 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | N'-[(4-cyanophenyl)methylidene]benzenesulfonohydrazide | HCID 1474568 | — |
Reaction Steps
Benzenesulfonyl hydrazine (20.5 g, 0.12 mole) was dissolved by warming in 110 ml absolute ethanol. p-Cyanobenzaldehyde (15.6 g, 0.12 mole) was separately dissolved in 50 ml of hot ethanol and added to the hydrazine solution. The resulting slurry was refluxed 0.5 hour, cooled and filtered to yield 28.1 g; m.p. 209°-213°. Recrystallization from CH3CN gave purified title product: 23.7 g; m.p. 210°-213°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04546113 |
| Source dataset | uspto-grants-1985_10 |
| ORD ID | ord-2f3ebd3da2dd45cf834f52d28bad5db4 |
| Source note | uspto-grants-1985_10 |