Sodium Hydroxide → HCID 20264122, compound

HRID 464112Notes

Reaction equation

HRID 464112 reaction equation
[NH2:1][C:2]([CH3:10])([CH2:5][CH2:6][CH:7]([CH3:9])[CH3:8])[C:3]#[N:4].Cl[N:12](Cl)[C:13]([CH3:21])([CH2:16][CH2:17][CH:18]([CH3:20])[CH3:19])[C:14]#[N:15].[OH-].[Na+]>O>[N:12]([C:13]([CH3:21])([CH2:16][CH2:17][CH:18]([CH3:20])[CH3:19])[C:14]#[N:15])=[N:1][C:2]([CH3:10])([CH2:5][CH2:6][CH:7]([CH3:9])[CH3:8])[C:3]#[N:4]

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 20264118HCID 20264118, compound2×HCID 20264121HCID 20264121, compound

Product 1

HCID 20264122HCID 20264122, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

30 g of 94% pure 2-amino-2,5-dimethylhexanenitrile is chlorinated in water at 1080 mv by the method of Example 2. To the resulting aqueous dispersion of 2-dichloroamino-2,5-dimethylhexanenitrile, following the method of Example 1, caustic soda, wetter, and a further 20 g of 2-amino-2,5-dimethylhexanenitrile are added and the suspension is filtered to yield 40.6 g of the title compound as a creamy white solid, mp 56°-58° C. (88%).

Workup

  1. filtrationthe suspension is filtered

Sources & evidence

ORD record
ord-98fcc72e7bd84a39bb42b908fde118cd
Source dataset
uspto-grants-1985_10
Patent number
US04546174

Reaction notes

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