HRID46412

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7918

Acetic anhydride

C4H6O3

结构：O=C(C=C1C=C(c2ccccc2)OC(c2ccccc2)=C1)c1ccccc1

HCID12272528

未命名化合物

结构：Cc1cc(-c2ccccc2)[o+]c2ccccc12.[O-][Cl+3]([O-])([O-])[O-]

HCID12334189

未命名化合物

PRODUCTS

生成物

结构：C(=C1C=C(c2ccccc2)OC(c2ccccc2)=C1)C(=Cc1cc(-c2ccccc2)[o+]c2ccccc12)c1ccccc1.[O-][Cl+3]([O-])([O-])[O-]

HCID74042279

未命名化合物

PROCEDURE

实验过程

A mixture of 1 g. 2,6-diphenyl-4-phenacylidene-4H-pyran, 1.3 g. of 4-methylflavylium perchlorate and 20 ml. of acetic anhydride was refluxed for 15 minutes, chilled and the solid was collected and purified by extraction. The resultant product had a melting point of 299°-300° C. and was identified as the above-noted pyrylium salt having an empirical formula of C41H29ClO6.

WORKUP

后处理

additionA mixture of 1 g
temperaturechilled
customthe solid was collected
custompurified by extraction

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-03da321513f0404792416c7c9c01b9a8
来源数据集: uspto-grants-1979_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04173473
来源说明: uspto-grants-1979_11

反应 SMILES

[C:1]1([C:7]2[O:8][C:9]([C:22]3[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=3)=[CH:10][C:11](=[CH:13][C:14]([C:16]3[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=3)=O)[CH:12]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:28]([O-:32])(=[O:31])(=[O:30])=[O:29].[CH3:33][C:34]1[C:43]2[C:38](=[CH:39][CH:40]=[CH:41][CH:42]=2)[O+:37]=[C:36]([C:44]2[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=2)[CH:35]=1.C(OC(=O)C)(=O)C>>[Cl:28]([O-:32])(=[O:31])(=[O:30])=[O:29].[C:22]1([C:9]2[O:8][C:7]([C:1]3[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=3)=[CH:12][C:11](=[CH:13][C:14]([C:16]3[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=3)=[CH:33][C:34]3[C:43]4[C:38](=[CH:39][CH:40]=[CH:41][CH:42]=4)[O+:37]=[C:36]([C:44]4[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=4)[CH:35]=3)[CH:10]=2)[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1