HRID46413

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID9548819

Pyrylium

C5H5O+

2 次

结构：[O-][Cl+3]([O-])([O-])[O-].c1cc[o+]cc1

HCID11446693

未命名化合物

结构：Cc1cc(-c2ccccc2)[o+]c2ccccc12.[O-][Cl+3]([O-])([O-])[O-]

HCID12334189

未命名化合物

PRODUCTS

生成物

结构：C1=CC(=CC(=Cc2cc(-c3ccccc3)[o+]c3ccccc23)c2ccccc2)c2ccccc2O1.[O-][Cl+3]([O-])([O-])[O-]

HCID178420217

未命名化合物

PROCEDURE

实验过程

This pyrylium salt was made in a manner identical to that set forth in Example 1 above, except the pyrylium perchlorate salt starting material of Example 1 was replaced with 4-methylflavylium perchlorate. The pyrylium salt product was identified as the above-noted salt having a melting point of 298°-299° C. and an empirical formula of C39H27ClO6.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b0a0b837376f41f1beed392fc8f332ac
来源数据集: uspto-grants-1979_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04173473
来源说明: uspto-grants-1979_11

反应 SMILES

[O+:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:7]([O-:11])(=[O:10])(=[O:9])=[O:8].[O+]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.Cl([O-])(=O)(=O)=O.[CH3:23][C:24]1[C:33]2[C:28](=[CH:29][CH:30]=[CH:31][CH:32]=2)[O+:27]=[C:26]([C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)[CH:25]=1>>[Cl:7]([O-:11])(=[O:10])(=[O:9])=[O:8].[O:1]1[C:6]2[CH:23]=[CH:24][CH:25]=[CH:26][C:5]=2[C:4](=[CH:13][C:14]([C:15]2[CH:33]=[CH:28][CH:29]=[CH:17][CH:16]=2)=[CH:23][C:24]2[C:33]3[C:28](=[CH:29][CH:30]=[CH:31][CH:32]=3)[O+:27]=[C:26]([C:34]3[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=3)[CH:25]=2)[CH:3]=[CH:2]1