HRID46427

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：COc1ccc(N)cc1-c1nn(C(C)=O)c2cc(C)nn12

HCID23457048

未命名化合物

HCID135574040

未命名化合物

PRODUCTS

生成物

结构：COc1ccc(N=Nc2ccc(O)c(C(=O)Nc3ccc(OC)c(-c4nn(C(C)=O)c5cc(C)nn45)c3)c2)cc1

HCID136398787

未命名化合物

PROCEDURE

实验过程

5-(4-Methoxyphenylazo)salicoyl chloride and 1-acetyl-3-(5-amino-2-methoxyphenyl)-6-methyl-1H-pyrazolo[3,2-c]-s-triazole were reacted together as described for the preparation of Dye 7. The product crystallized as the monohydrate from aqueous pyridine, m.p. 282°-3°, λmax (methanol)=350 nm.

WORKUP

后处理

customas described for the preparation of Dye 7
customThe product crystallized as the monohydrate from aqueous pyridine, m.p. 282°-3°, λmax (methanol)=350 nm

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-a29d92bbdb384025b758a3900a13cf21
来源数据集: uspto-grants-1979_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04173478
来源说明: uspto-grants-1979_11

反应 SMILES

[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([N:9]=[N:10][C:11]2[CH:19]=[C:15]([C:16](Cl)=[O:17])[C:14]([OH:20])=[CH:13][CH:12]=2)=[CH:5][CH:4]=1.[C:21]([N:24]1[C:28]2=[CH:29][C:30]([CH3:32])=[N:31][N:27]2[C:26]([C:33]2[CH:38]=[C:37]([NH2:39])[CH:36]=[CH:35][C:34]=2[O:40][CH3:41])=[N:25]1)(=[O:23])[CH3:22]>>[C:21]([N:24]1[C:28]2=[CH:29][C:30]([CH3:32])=[N:31][N:27]2[C:26]([C:33]2[CH:38]=[C:37]([NH:39][C:16](=[O:17])[C:15]3[CH:19]=[C:11]([N:10]=[N:9][C:6]4[CH:7]=[CH:8][C:3]([O:2][CH3:1])=[CH:4][CH:5]=4)[CH:12]=[CH:13][C:14]=3[OH:20])[CH:36]=[CH:35][C:34]=2[O:40][CH3:41])=[N:25]1)(=[O:23])[CH3:22]