m-Chloroperbenzoic acid → HCID 13556882, compound

Participants

Reaction Steps

A solution of 1.4 g (5.5 mmole) of 8-chloro-4,5-dihydro-1-phenyl-3H-2-benzazepine and 1.4 g (7 mmole) of 85% m-chloroperbenzoic acid in 50 ml of methylene chloride was stirred at room temperature for 18 hr. The reaction mixture was washed with dilute aqueous sodium hydroxide and the organic layer was separated, dried over anhydrous sodium sulfate and concentrated in vacuo to dryness. The residue was crystallized from ether to give a colorless solid, mp 120°-125° C. Recrystallization from ether gave colorless prisms, mp 142°-143° C.

Provenance & Evidence