m-Chloroperbenzoic acid → HCID 13556886, compound

Participants

Reaction Steps

A solution of 6.9 g (20.7 mmole) of 8-chloro-5-bromo-1-phenyl-3H-2-benzazepine and 6 g (29 mmole) of 85% m-chloroperbenzoic acid in 100 ml of methylene chloride was stirred at room temperature for 1 hr. The mixture was washed with cold dilute sodium hydroxide, dried over anhydrous sodium sulfate and concentrated at reduced pressure to dryness. The residue was crystallized from ether to give a white solid, mp 184°-185° C. Recrystallization from ether gave colorless prisms, mp 185°-186° C. dec.

Provenance & Evidence