Hydrazine → HCID 13533720, compound

HRID 465127Notes

Reaction equation

HRID 465127 reaction equation
Cl[C:2]1[C:7]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][N:9]=2)=[CH:6][CH:5]=[CH:4][N:3]=1.[NH2:14][NH2:15]>N1C=CC=CC=1>[NH:14]([C:2]1[C:7]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][N:9]=2)=[CH:6][CH:5]=[CH:4][N:3]=1)[NH2:15]

Participants

4

Reactant 2

HCID 9321HydrazineHCID 1329872693297-77-9

Product 1

HCID 13533720HCID 13533720, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

A mixture of 2.5 g of 2'-chloro-2,3'-bipyridine, 12.6 ml of anhydrous hydrazine and 50 ml of pyridine was refluxed for 36 hours and concentrated under vacuum to a gum. The gum was dissolved in methylene chloride, treated with activated carbon, dried over sodium sulfate and the solvent removed. The residue was crystallized from etherhexane to give 2.1 g of 2'-hydrazino-2,3'-bipyridine as yellow crystals, mp 64°-65° C.

Workup

  1. temperaturewas refluxed for 36 hours
  2. concentrationconcentrated under vacuum to a gum
  3. dissolutionThe gum was dissolved in methylene chloride
  4. additiontreated with activated carbon
  5. dry with materialdried over sodium sulfate
  6. customthe solvent removed
  7. customThe residue was crystallized from etherhexane

Sources & evidence

ORD record
ord-2bf3d648e07e40b2bed0000f3e55bac8
Source dataset
uspto-grants-1985_10
Patent number
US04550166

Reaction notes

Loading…