Bicyclooctyl → 6,9-Methylene-11,15-dihydroxy-20-isopropylideneprost-5,13-dienoic acid

HRID 465290Notes

Reaction equation

HRID 465290 reaction equation
[CH2:1]1[CH:12]2[CH2:13][CH:14]([OH:29])[C@H:15]([CH:16]=[CH:17][CH:18]([OH:28])[CH2:19][CH:20](C)[CH2:21][CH2:22][CH:23]=[C:24]([CH3:26])[CH3:25])[C@H:11]2[CH2:10][C:2]1=[CH:3][CH2:4][CH2:5][CH2:6][C:7]([OH:9])=[O:8].C1(C2CCCCCCC2)CCCCCCC1>>[CH2:1]1[CH:12]2[CH2:13][CH:14]([OH:29])[C@H:15]([CH:16]=[CH:17][CH:18]([OH:28])[CH2:19][CH2:20][CH2:21][CH2:22][CH:23]=[C:24]([CH3:25])[CH3:26])[C@H:11]2[CH2:10][C:2]1=[CH:3][CH2:4][CH2:5][CH2:6][C:7]([OH:9])=[O:8]

Participants

3

Reactant 2

HCID 524587BicyclooctylHCID 543343796,9-Methylene-11,15-dihydroxy-17-methyl-20-isopropylideneprost-5,13-dienoic acid

Product 1

HCID 542919686,9-Methylene-11,15-dihydroxy-20-isopropylideneprost-5,13-dienoic acid

Procedure

6,9-methylene-11,15-dihydroxy-17-methyl-20-isopropylideneprost-5,13-dienoic acid {otherwise known as 7-(4-carboxybutylidene)-3-hydroxy-2-(3-hydroxy-5,9-dimethyl-1,8-decadienyl)-[3.3.0]-bicyclooctane};

Sources & evidence

ORD record
ord-dde0a09e19d9453eab1603b6f353fd0d
Source dataset
uspto-grants-1992_10
Patent number
US05153003

Reaction notes

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