Aluminium lithium hydride → HCID 19874939, compound

HRID 465670Notes

Reaction equation

HRID 465670 reaction equation
C[O:2][C:3](=O)[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH:10]([NH:17][CH2:18][C:19]([NH:21][C:22]2[C:27]([CH:28]([CH3:30])[CH3:29])=[CH:26][CH:25]=[CH:24][C:23]=2[CH:31]([CH3:33])[CH3:32])=[O:20])[C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)[CH:5]=1.[H-].[H-].[H-].[H-].[Li+].[Al+3]>>[CH3:30][CH:28]([C:27]1[CH:26]=[CH:25][CH:24]=[C:23]([CH:31]([CH3:32])[CH3:33])[C:22]=1[NH:21][C:19](=[O:20])[CH2:18][NH:17][CH:10]([C:6]1[CH:7]=[CH:8][CH:9]=[C:4]([CH2:3][OH:2])[CH:5]=1)[C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)[CH3:29]

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 56983731HCID 56983731, compound

Product 1

HCID 19874939HCID 19874939, compound

Procedure

The title compound was prepared by the reduction of the product of Example 149 by LiAlH4 at room temperature, mp 57°-62° C.

Sources & evidence

ORD record
ord-eb121deacbee4e3c99fa8ef8c43dd708
Source dataset
uspto-grants-1992_10
Patent number
US05153226

Reaction notes

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