HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitric Acid → 5-Aminoacenaphthene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitric Acid | HCID 944 | — |
| Reactant | Acenaphthene | HCID 6734 | — |
| Reactant | Hydrazine | HCID 9321 | — |
| Reactant | 5-Nitroacenaphthene | HCID 11769 | — |
| Reactant | Tin atom | HCID 5352426 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Hydrochloric Acid | HCID 313 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 5-Aminoacenaphthene | HCID 62547 | — |
Reaction Steps
5-Nitroacenaphthene is made by nitrating acenaphthene with nitric acid in the presence of acetic acid according to the method of Rowe and Davies, J. Chem. Soc. 117, 1346 (1920). Standard reduction methods using tin or stannous chloride in hydrochloric acid or by using Raney nickel with ethanol or hydrazine produces 5-aminoacenaphthene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04174342 |
| Source dataset | uspto-grants-1979_11 |
| ORD ID | ord-1a06f9ffbc2c46afaf47b657be09d7f6 |
| Source note | uspto-grants-1979_11 |