HRID466949

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8221

1-Octadecanol

C18H38O

HCID20089828

2-Fluorotetracene-5,12-dione

C18H9FO2

PRODUCTS

生成物

结构：CCCCCCCCCCCCCCCCCCOc1ccc2c(c1)C(=O)c1cc3ccccc3cc1C2=O

HCID19812763

未命名化合物

PROCEDURE

实验过程

The procedure is analogous to Example 1, and 2-fluorotetracene-5,12-dione is reacted with 1-octadecanol, the 2-n-octadecyloxytetracene-5,12-dione obtained is converted into the corresponding diacetate by reductive acetylation, and the latter is reacted with sulfur int eh presence of p-toluenesulfonic acid to form 2-n-octadecyloxytetracene-5,6,11,12-tetrathiotetracene. The individual reaction products have the following characteristic data:

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-80277538c25a404db0fc52f5e8a70224
来源数据集: uspto-grants-1992_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05158829
来源说明: uspto-grants-1992_10

反应 SMILES

F[C:2]1[CH:19]=[CH:18][C:17]2[C:16](=[O:20])[C:15]3[C:6](=[CH:7][C:8]4[C:13]([CH:14]=3)=[CH:12][CH:11]=[CH:10][CH:9]=4)[C:5](=[O:21])[C:4]=2[CH:3]=1.[CH2:22]([OH:40])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39]>>[CH2:22]([O:40][C:2]1[CH:19]=[CH:18][C:17]2[C:16](=[O:20])[C:15]3[C:6](=[CH:7][C:8]4[C:13]([CH:14]=3)=[CH:12][CH:11]=[CH:10][CH:9]=4)[C:5](=[O:21])[C:4]=2[CH:3]=1)[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39]