HRID467217

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10909563

3,4-DIETHYLPYRROLE

C8H13N

结构：CCOC(=O)Cc1c(COC(C)=O)[nH]c(C(=O)OCc2ccccc2)c1C

HCID14541573

未命名化合物

PRODUCTS

生成物

结构：CCOC(=O)Cc1c(Cc2[nH]c(Cc3[nH]c(C(=O)OCc4ccccc4)c(C)c3CC(=O)OCC)c(CC)c2CC)[nH]c(C(=O)OCc2ccccc2)c1C

HCID14541574

未命名化合物

PROCEDURE

实验过程

condensing two molecular equivalents of benzyl 5-(acetoxymethyl)-4-ethoxycarbonylmethyl-3-methylpyrrole-2-carboxylate with 3,4-diethyl pyrrole under acidic conditions to produce 2,5-bis(5-benzyloxycarbonyl-3-ethoxycarbonylmethyl -4-methylpyrrol-2-ylmethyl)-3,4-diethylpyrrole;

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-53f76ab21ef846afb489e3386cfea4bf
来源数据集: uspto-grants-1992_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05159065
来源说明: uspto-grants-1992_10

反应 SMILES

C(O[CH2:5][C:6]1[NH:10][C:9]([C:11]([O:13][CH2:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[O:12])=[C:8]([CH3:21])[C:7]=1[CH2:22][C:23]([O:25][CH2:26][CH3:27])=[O:24])(=O)C.[CH2:28]([C:30]1[C:34]([CH2:35][CH3:36])=[CH:33][NH:32][CH:31]=1)[CH3:29]>>[CH2:14]([O:13][C:11]([C:9]1[NH:10][C:6]([CH2:5][C:31]2[NH:32][C:33]([CH2:5][C:6]3[NH:10][C:9]([C:11]([O:13][CH2:14][C:15]4[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=4)=[O:12])=[C:8]([CH3:21])[C:7]=3[CH2:22][C:23]([O:25][CH2:26][CH3:27])=[O:24])=[C:34]([CH2:35][CH3:36])[C:30]=2[CH2:28][CH3:29])=[C:7]([CH2:22][C:23]([O:25][CH2:26][CH3:27])=[O:24])[C:8]=1[CH3:21])=[O:12])[C:15]1[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1