Thionyl Chloride → HCID 14699636, compound

HRID 467324Notes

Reaction equation

HRID 467324 reaction equation
[F:1][C:2]1([Cl:9])[CH2:4][C:3]1([CH3:8])[C:5](O)=[O:6].S(Cl)([Cl:12])=O>>[F:1][C:2]1([Cl:9])[CH2:4][C:3]1([CH3:8])[C:5]([Cl:12])=[O:6]

Participants

3

Reactant 2

HCID 24386Thionyl Chloride2×HCID 14699634128230-79-5

Product 1

HCID 14699636HCID 14699636, compoundYield 97%

Procedure

In a distillation equipment, a mixture of 51 g (0.33 mol) of 2-fluoro-2-chloro-1-methylcyclopropanecarboxylic acid and 60 g (0.5 mol) of thionyl chloride is heated slowly with stirring, during which process excess thionyl chloride distils over first and the desired product later. In this manner, 54 g (97% of theory) of 2-fluoro-2-chloro-1-methylcyclopropanecarbonyl chloride are obtained in the form of a liquid of boiling point 82-85° C./ 100 mbar.

Workup

  1. temperatureis heated slowly
  2. customdistils over first and the desired product later

Sources & evidence

ORD record
ord-4072ad8f472447ed97e0f4eb2edbd195
Source dataset
uspto-grants-1992_10
Patent number
US05159111

Reaction notes

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