Water → (E)-2-(5-chloro-2,4-dinitrophenyl)-N,N-dimethylethenamine

Participants

Role	Name	HCID	Charge
Reactant	Water	HCID 962	—
Reactant	Dimethylacetamide	HCID 31374	—
Reactant	5-Chloro-2,4-dinitrotoluene	HCID 253802	—
Solvent	Dimethylformamide	HCID 6228	—
Product	(E)-2-(5-chloro-2,4-dinitrophenyl)-N,N-dimethylethenamine	HCID 59129321	72.4%

Reaction Conditions

Temperature	100 °C

Reaction Steps

A mixture of 1-chloro-5-methyl-2,4-dinitro-benzene (11.6 g, 50.0 mmol), DMA (11.9 g, 100 mmol) in DMF (50 mL) was heated at 100° C. for 4 h. The solution was cooled and poured into water. The precipitated red solid was collected by filtration, washed with water, and dried to give (E)-2-(5-chloro-2,4-dinitrophenyl)-N,N-dimethylethenamine (9.84 g, 72%).

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US08623905B2
Source dataset	uspto-grants-2014_01
ORD ID	ord-1ffdeb5469e2432fa212b0007002573e
Source note	uspto-grants-2014_01