Dodecane → HCID 58202941, compound

Participants

Reaction Conditions

Reaction Steps

To 4.2 g of the resulting 6-bromo-4′-(naphthalen-2-yl)-[2,2′;6′,2″]terpyridine were added 1.6 g of 5H-pyrido[4,3-b]indole, 0.3 g of a copper powder, 4.0 g of potassium carbonate, 0.3 mL of dimethyl sulfoxide, and 10 mL of n-dodecane, followed by heating and stirring at 150° C. for 8 hours. After cooling to room temperature, 80 mL of chloroform was added thereto to remove an insoluble matter by filtration, and the filtrate was concentrated under a reduced pressure to obtain a crude product. The crude product was purified by column chromatography (carrier: NH silica gel, eluent: hexane/chloroform) to obtain 2.2 g (yield, 43%) of 4′-(naphthalen-2-yl)-6-(5H-pyrido[4,3-b]indol-5-yl)-[2,2′;6′,2″]terpyridine (Compound 27) as a white powder.

Provenance & Evidence