3-Furanmethanol → HCID 66745607, compound

HRID 471654Notes

Reaction equation

HRID 471654 reaction equation
[N+]([C:4]1[CH:11]=[CH:10][CH:9]=[C:8]([N+:12]([O-:14])=[O:13])[C:5]=1[C:6]#[N:7])([O-])=O.[O:15]1[CH:19]=[CH:18][C:17]([CH2:20][OH:21])=[CH:16]1>>[N+:12]([C:8]1[CH:9]=[CH:10][CH:11]=[C:4]([O:21][CH2:20][C:17]2[CH:18]=[CH:19][O:15][CH:16]=2)[C:5]=1[C:6]#[N:7])([O-:14])=[O:13]

Participants

3

Reactant 2

HCID 204493-FuranmethanolHCID 520718Dinitrobenzonitrile

Product 1

HCID 66745607HCID 66745607, compoundYield 100%

Procedure

Prepared as in Example 111c from 2,6-dinitrobenzonitrile and 3-furanmethanol in 100% yield. 1H NMR (400 MHz, d-DMSO) δ 5.27 (s, 2H), 6.59 (s, 1H), 7.69 (s, 1H), 7.91-7.84 (m, 4H).

Sources & evidence

ORD record
ord-efcb72c22df84de4b0419d90fb84383d
Source dataset
uspto-grants-2014_01
Patent number
US08633186B2

Reaction notes

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