huagongshe.com
HRID471726

反应详情

EQUATION

反应方程式

HRID 471726 的结构方程式

REACTANTS

反应物

2
结构：CC(C)(C)[Si](C)(C)OCCCCO
HCID186403

4-(Dimethyl-tert-butylsilyl)oxybutan-1-ol

C10H24O2Si

结构：N#Cc1c([N+](=O)[O-])cccc1[N+](=O)[O-]
HCID520718

Dinitrobenzonitrile

C7H3N3O4

PRODUCTS

生成物

1
结构：CC(C)(C)[Si](C)(C)OCCCCOc1cccc([N+](=O)[O-])c1C#N
HCID66747043

未命名化合物

收率 25%

PROCEDURE

实验过程

Prepared as in Example 215c from 4-(tert-butyldimethyl-silyloxy)butan-1-ol and 2,6-dinitrobenzonitrile in 25% yield as a pale yellow solid. 1H NMR (400 MHz, DMSO-d6) δ 0.01 (s, 6H), 0.81-0.83 (m, 9H), 1.61-1.66 (m, 2H), 1.76-1.81 (m, 2H), 3.63 (t, J=6.8 Hz, 2H), 4.26 (t, J=6.4 Hz, 2H), 7.68-7.70 (m, 1H), 7.84-7.89 (m, 2H).