HCID 18990113, compound → HCID 19995384, compound

HRID 477288Notes

Reaction equation

HRID 477288 reaction equation
C[O:2][C:3]1[C:12]2[C:7](=[CH:8][CH:9]=[C:10]([C:13]3[CH:22]=[CH:21][C:20]4[C:19]([CH3:24])([CH3:23])[CH2:18][CH2:17][C:16]([CH3:26])([CH3:25])[C:15]=4[CH:14]=3)[CH:11]=2)[CH:6]=[C:5]([C:27]([OH:29])=[O:28])[CH:4]=1.OC1C2C(=CC=C(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)C=2)C(C)=C(C(O)=O)C=1.OC1C2C(=CC=C(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)C=2)C(C)(C([O-])=O)C(C)C=1.SC1C2C(=CC=C(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)C=2)C(C)=C(C(O)=O)C=1.CC1C2C(=CC(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)=CC=2)C=CC=1C(O)=O.CC1C2C(=CC(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)=CC=2)C=CC=1CO.CC1C2C(=CC(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)=CC=2)C=CC=1C=O.CC1C2C(=CC(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)=CC=2)C=CC=1COCC1C=CC2C(=CC=C(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)C=2)C=1C.CC1C2C(=CC(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)=CC=2)C=CC=1C(C1C=CC2C(=CC=C(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)C=2)C=1C)=O.C(OCC1C=CC2C(=CC=C(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)C=2)C=1C)(=O)C.C(OCC1C=CC2C(=CC=C(C3C=CC4C(C)(C)CCC(C)(C)C=4C=3)C=2)C=1C)(=O)CC>>[OH:2][C:3]1[C:12]2[C:7](=[CH:8][CH:9]=[C:10]([C:13]3[CH:22]=[CH:21][C:20]4[C:19]([CH3:23])([CH3:24])[CH2:18][CH2:17][C:16]([CH3:25])([CH3:26])[C:15]=4[CH:14]=3)[CH:11]=2)[CH:6]=[C:5]([C:27]([OH:29])=[O:28])[CH:4]=1

Participants

12

Reactant 11

HCID 18990113HCID 18990113, compoundHCID 19837479HCID 19837479, compoundHCID 19995385HCID 19995385, compoundHCID 19995388HCID 19995388, compoundHCID 19995397HCID 19995397, compound2×HCID 19995399HCID 19995399, compoundHCID 23326809HCID 23326809, compoundHCID 54174974HCID 54174974, compoundHCID 54501721HCID 54501721, compoundHCID 67944229HCID 67944229, compound2×HCID 86741533HCID 86741533, compound

Product 1

HCID 19995384HCID 19995384, compound

Procedure

4-methoxy-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthoic acid; 4-acetoxy-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-methyl naphtoate; 4-acetoxy-1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8,-tetramethyl-2-naphthyl)-2-methyl naphthoate; 4-hydroxy-1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthoic acid; 4-hydroxy-1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-methylnaphthoate; 4-mercapto-1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthoic acid; 1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthoic acid; 1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthalene methanol; 1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthaldehyde; α-methyl[-1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)]-2-naphthalene methanol; α-ethyl-[1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)]-2-naphthalene methanol; α-n-propyl[-1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)]-2 -naphthalene methanol; methyl, 1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthylmethyl ether; ethyl, 1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthylmethyl ether; methyl, 1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthyl ketone; ethyl, 1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthyl ketone; 1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthylmethyl acetate; 1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)-2-naphthylmethyl propionate; α-methyl-[1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)]-2-naphthylmethyl acetate; and α-methyl[-1-methyl-6-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)]-2-naphthylmethyl propionate.

Sources & evidence

ORD record
ord-146f6b15c99f4fcd8153cf592f517ed4
Source dataset
uspto-grants-1989_12
Patent number
US04886907

Reaction notes

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