HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl bromoacetate → Acetic acid, (butylthio)-, ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl bromoacetate | HCID 7748 | — |
| Reactant | Butanethiol | HCID 8012 | — |
| Reactant | Acetic acid, (phenylthio)-, ethyl ester | HCID 97312 | — |
| Reactant | Sodium ethoxide | HCID 2723922 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | Acetic acid, (butylthio)-, ethyl ester | HCID 10749796 | — |
Reaction Steps
The procedure is as in Example 2 for the preparation of ethyl (phenylthio)acetate, starting with n-butylmercaptan (10.7 cc), a 2M ethanolic solution of sodium ethylate (50 cc) and ethyl bromoacetate (16.7 g) in ethanol (100 cc). Ethyl (n-butylthio)acetate (15.4 g) is thereby obtained, and is used in the crude state in the subsequent syntheses.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04886835 |
| Source dataset | uspto-grants-1989_12 |
| ORD ID | ord-7518eede966246c28649c125fa10cb27 |
| Source note | uspto-grants-1989_12 |