HCID 14770197, compound → HCID 14770199, compound

HRID 477907Notes

Reaction equation

HRID 477907 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([C@H:10]2[CH2:14][CH2:13][C@H:12]([C:15]3[CH:20]=[CH:19][C:18]([N+:21]([O-])=O)=[CH:17][CH:16]=3)[O:11]2)=[CH:6][CH:5]=1)([O-])=O>CCO.[Pd]>[NH2:21][C:18]1[CH:19]=[CH:20][C:15]([C@H:12]2[CH2:13][CH2:14][C@H:10]([C:7]3[CH:6]=[CH:5][C:4]([NH2:1])=[CH:9][CH:8]=3)[O:11]2)=[CH:16][CH:17]=1

Participants

4

Reactant 1

HCID 14770197HCID 14770197, compound

Product 1

HCID 14770199HCID 14770199, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

A mixture of 8 g of Compound 1 and 1 g of 5% Pd/C in 100 ml of EtOH is hydrogenated at 20 psi for 2 hours. The desired product is obtained after removal of solvent.

Sources & evidence

ORD record
ord-141b802abeb64c418c4b877b2d01811f
Source dataset
uspto-grants-1989_12
Patent number
US04889868

Reaction notes

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