HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carvone, (+-)- → 4a-Carboethoxy-7-hydroxy-4,4a,5,6-tetrahydro-2(3H)-naphthalenone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carvone, (+-)- | HCID 7439 | — |
| Reactant | 1-Penten-3-one | HCID 15394 | — |
| Reactant | Ethyl 3-chloropropionate | HCID 69341 | — |
| Reactant | 4-Carbethoxy-3-methyl-2-cyclohexen-1-one | HCID 79020 | — |
| Product | 4a-Carboethoxy-7-hydroxy-4,4a,5,6-tetrahydro-2(3H)-naphthalenone | HCID 13950339 | — |
Reaction Steps
This material is prepared according to the procedure for Preparation 6 wherein Hagemann's ester (ethyl 2-methyl-4-oxocyclohex-2-enyl-1-carboxylate) is substituted for carvone and ethyl 3-chloropropionate is substituted for ethyl vinyl ketone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04889947 |
| Source dataset | uspto-grants-1989_12 |
| ORD ID | ord-3f6f4f62c9f14855a8983544f3155d68 |
| Source note | uspto-grants-1989_12 |