HRID478921

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7923

2,5-Furandione

C4H2O3

HCID78949

Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

C8H10O2

HCID9964188

未命名化合物

结构：CCC1(C23C=CC(CC2C(=O)[O-])C3)CC2CC1C1CCCC21

HCID18003142

未命名化合物

PRODUCTS

生成物

结构：CCC1(C23C=CC(CC2C(=O)[O-])C3)CC2CC1C1CCCC21.O=C(O)C1CC2C=CC1C2.O=C1C=CC(=O)O1.O=C1OC(=O)C2C1[C@@H]1C=C[C@H]2C1

HCID131724198

未命名化合物

PROCEDURE

实验过程

Polymerization and separation were carried out in the same manner as in Example 18 using 80 mmol of 8-ethyl-8-tricyclo[5.2.1.02,6]decanyl-5-norbornene-2-carboxylate prepared in Example 3, 100 mmol of maleic anhydride, 15 mmol of cis-5-norbornene-endo-2,3-dicarboxylic anhydride and 5 mmol of 5-norbornene-2-carboxylic acid, to separate 6.7 g of a polymer.

WORKUP

后处理

customPolymerization and separation
customto separate 6.7 g of a polymer

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-54edceb46eb54ca48f066e6b17414304
来源数据集: uspto-grants-2003_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06642336B1
来源说明: uspto-grants-2003_11

反应 SMILES

[CH2:1]([C:3]1([C:13]23[CH2:19][CH:16]([CH:17]=[CH:18]2)[CH2:15][CH:14]3[C:20]([O-:22])=[O:21])[CH2:11][CH:10]2[CH2:12][CH:4]1[CH:5]1[CH:9]2[CH2:8][CH2:7][CH2:6]1)[CH3:2].[C:23]1(=[O:29])[O:28][C:26](=[O:27])[CH:25]=[CH:24]1.[CH2:30]1[C@@H:34]2[CH:35]3[C:40](=[O:41])[O:39][C:37](=[O:38])[CH:36]3[C@H:31]1[CH:32]=[CH:33]2.[CH:42]12[CH2:48][CH:45]([CH:46]=[CH:47]1)[CH2:44][CH:43]2[C:49]([OH:51])=[O:50]>>[CH2:1]([C:3]1([C:13]23[CH2:19][CH:16]([CH:17]=[CH:18]2)[CH2:15][CH:14]3[C:20]([O-:22])=[O:21])[CH2:11][CH:10]2[CH2:12][CH:4]1[CH:5]1[CH:9]2[CH2:8][CH2:7][CH2:6]1)[CH3:2].[C:26]1(=[O:27])[O:28][C:23](=[O:29])[CH:24]=[CH:25]1.[CH2:30]1[C@@H:34]2[CH:35]3[C:40](=[O:41])[O:39][C:37](=[O:38])[CH:36]3[C@H:31]1[CH:32]=[CH:33]2.[CH:42]12[CH2:48][CH:45]([CH:46]=[CH:47]1)[CH2:44][CH:43]2[C:49]([OH:51])=[O:50]