HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methane, dichloromethoxy- → 4-Benzyloxy-5,6,7,8-tetrahydronaphthalene-1-carboxaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methane, dichloromethoxy- | HCID 21004 | — |
| Reactant | 5-(Benzyloxy)-1,2,3,4-tetrahydronaphthalene | HCID 22647606 | — |
| Catalyst | Titanium Tetrachloride | HCID 24193 | — |
| Product | 4-Benzyloxy-5,6,7,8-tetrahydronaphthalene-1-carboxaldehyde | HCID 22647615 | — |
Reaction Steps
In analogy to the procedure described in examples 91 b], 5-benzyloxy-1,2,3,4-tetrahydro-naphthalene [J . Org. Chem. (2001), 66(5), 1775-1780] was treated with dichloromethyl methyl ether and titanium tetrachloride to give 4-benzyloxy-5,6,7,8-tetrahydro-naphthalene-1-carbaldehyde as yellow solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06642389B2 |
| Source dataset | uspto-grants-2003_11 |
| ORD ID | ord-b079adaf63bc4c20ac4ae2b6f6b406ad |
| Source note | uspto-grants-2003_11 |