3-Hydroxy-7-phenoxyheptanoic acid → 11-Phenoxyundecanoic acid

HRID 479918Notes

Reaction equation

HRID 479918 reaction equation
O[CH:2]([CH2:7][CH2:8][O:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[CH2:3][C:4](O)=O.O[CH:17]([CH2:22][CH2:23][CH2:24]COC1C=CC=CC=1)[CH2:18][C:19]([OH:21])=[O:20].OC(CCCCCCOC1C=CC=CC=1)CC(O)=O>>[O:9]([CH2:8][CH2:7][CH2:2][CH2:3][CH2:4][CH2:24][CH2:23][CH2:22][CH2:17][CH2:18][C:19]([OH:21])=[O:20])[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

Participants

4

Reactant 3

HCID 187675233-Hydroxy-7-phenoxyheptanoic acidHCID 220240373-Hydroxy-9-phenoxynonanoic acidHCID 220240393-Hydroxy-5-phenoxypentanoic acid

Product 1

HCID 8159711-Phenoxyundecanoic acid

Procedure

Result indicates that PHA copolymer containing three units of 3-hydroxy-5-phenoxyvaleric acid (3HPxV), 3-hydroxy-7-phenoxyheptanoic acid (3HPxHp) and 3-hydroxy-9-phenoxynonanoic acid (3HPxN) can be produced by the strain H45 with a substrate 11-phenoxyundecanoic acid.

Workup

  1. customResult

Sources & evidence

ORD record
ord-25108a8b61374259831d8f65ab55ed2b
Source dataset
uspto-grants-2003_11
Patent number
US06649381B1

Reaction notes

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