HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 480995Generated: October 26, 2026
Phenol → 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-(4-hydroxyphenyl)fluorene
https://huagongshe.com/reaction/480995
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Phenol | HCID 996 | — |
| Reactant | Sulfuric Acid | HCID 1118 | — |
| Reactant | (+-)-2-Mercaptopropionic acid | HCID 62326 | — |
| Reactant | 2,7-Dibromo-9-(2,5-dimethylphenyl)-9H-fluoren-9-OL | HCID 18766843 | — |
| Solvent | Methanol | HCID 887 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-(4-hydroxyphenyl)fluorene | HCID 18766847 | — |
Reaction Steps
9.5 g of phenol were mixed with 22.2 g of 2,7-dibromo-9-(2,5-dimethylphenyl)fluoren-9-ol, 25 ml of toluene and 0.1 ml of mercapto-propionic acid. 5 ml of concentrated sulfuric acid were subsequently added dropwise. The batch was then stirred at 60° C. for about 2 hours, and finally 100 ml of MeOH and 100 ml of water were added. The solid was filtered off with suction and further purified by stirring with ethanol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06653438B1 |
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| Source dataset | uspto-grants-2003_11 |
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| ORD ID | ord-4e3ca63617244fcb8644a6494c84f657 |
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| Source note | uspto-grants-2003_11 |
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