HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Iodide → 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-[4-(3,7-dimethyloctyloxy)phenyl]-fluorene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Iodide | HCID 5238 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | 1-Chloro-3,7-dimethyloctane | HCID 227360 | — |
| Reactant | 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-(4-hydroxyphenyl)fluorene | HCID 18766847 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-[4-(3,7-dimethyloctyloxy)phenyl]-fluorene | HCID 18766842 | — |
Reaction Steps
52 g of 2,7-dibromo-9-(2,5-dimethylphenyl)-9-(4-hydroxyphenyl)fluorene were refluxed with 18 g of 3,7-dimethyloctyl chloride, 80 ml of ethanol, 7 g of KOH and 1 g of NaI for 5 days. According to TLC, the reaction was complete after this time. The solvent was stripped off, ethyl acetate was added, and the precipitate was filtered off with suction and rinsed a number of times with ethyl acetate. The organic phase was dried, and the solvent was stripped off.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06653438B1 |
| Source dataset | uspto-grants-2003_11 |
| ORD ID | ord-6d04b460c8404279aa774d3bf11f9768 |
| Source note | uspto-grants-2003_11 |