HRID482815

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID19147

Benzoic acid, 4-octyl-

C15H22O2

HCID24386

Thionyl chloride

Cl2OS

HCID170865

Benzoyl chloride, 4-octyl-

C15H21ClO

HCID13907537

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCc1ccc(C(=O)Oc2ccc(-c3ccc(C(=O)OCC(C)CC)cc3)cc2)cc1

HCID13530953

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1049

Pyridine

C5H5N

溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

p-n-Octylbenzoic acid chloride prepared from 7 g of p-n-octylbenzoic acid and excess thionyl chloride was dissolved in toluene, and the solution was admixed with a pyridine solution of 8.3 g of said 4-hydroxy-4'-biphenylcarboxylic acid 2-methylbutyl ester for reaction at 80° C. for 3 hours. The crude product was obtained in the same manner as described in Example 1 and recrystallized twice from ethyl acetate to obtain p-n-octylbenzoic acid 4'-(2-methylbutoxycarbonyl)-4-biphenylyl ester.

WORKUP

后处理

customThe crude product was obtained in the same manner
customrecrystallized twice from ethyl acetate

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-9936b72136db40618d3c169a9437e706
来源数据集: uspto-grants-1986_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04576732
来源说明: uspto-grants-1986_03

反应 SMILES

C(C1C=CC(C(Cl)=O)=CC=1)CCCCCCC.[CH2:18]([C:26]1[CH:34]=[CH:33][C:29]([C:30]([OH:32])=[O:31])=[CH:28][CH:27]=1)[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25].S(Cl)(Cl)=O.[CH3:39][CH:40]([CH2:58][CH3:59])[CH2:41][O:42][C:43]([C:45]1[CH:50]=[CH:49][C:48]([C:51]2[CH:56]=[CH:55][C:54](O)=[CH:53][CH:52]=2)=[CH:47][CH:46]=1)=[O:44]>C1(C)C=CC=CC=1.N1C=CC=CC=1>[CH3:39][CH:40]([CH2:58][CH3:59])[CH2:41][O:42][C:43]([C:45]1[CH:50]=[CH:49][C:48]([C:51]2[CH:56]=[CH:55][C:54]([O:31][C:30](=[O:32])[C:29]3[CH:28]=[CH:27][C:26]([CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])=[CH:34][CH:33]=3)=[CH:53][CH:52]=2)=[CH:47][CH:46]=1)=[O:44]