HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Chloro-2-methyl-1-propene → 2,5,5,8-Tetramethylnona-1,6,7-trien-4-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Chloro-2-methyl-1-propene | HCID 11241 | — |
| Reactant | 2,5,5-Trimethylocta-1,6,7-trien-4-ol | HCID 3699416 | — |
| Reactant | 3,4-Hexadienal, 2,2,5-trimethyl- | HCID 11094698 | — |
| Product | 2,5,5,8-Tetramethylnona-1,6,7-trien-4-ol | HCID 13456442 | 92% |
Reaction Steps
2,5,5,8-tetramethylnona-1,6,7-trien-4-ol (2b) was prepared as described for 2a from 8.72 g (0.36 mole) of Mg, 32.65 g (0.36 mole) of β-methylallyl chloride and 16.61 g (0.12 mole) of 1b. The work up resulted in 21.44 g (92%) of 2b. Bp. 61°-2° C./0.3 mm Hg, nD16 1.4810.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04578484 |
| Source dataset | uspto-grants-1986_03 |
| ORD ID | ord-a639dfa80baf4508a146b51a54faa398 |
| Source note | uspto-grants-1986_03 |