3,3,5-Trimethylcyclohexanone → (1,1'-Biphenyl)-2,3'-diol

HRID 483859Notes

Reaction equation

HRID 483859 reaction equation
C[C:2]1([CH3:9])[CH2:7][CH2:6][CH2:5][C:4](=[O:8])[CH2:3]1.C[CH:11]1[CH2:17][C:16](C)(C)C[C:13](=[O:14])[CH2:12]1>>[CH:17]1[CH:16]=[C:9]([C:2]2[CH:7]=[CH:6][CH:5]=[C:4]([OH:8])[CH:3]=2)[C:13]([OH:14])=[CH:12][CH:11]=1

Participants

3

Reactant 2

HCID 133983,3,5-TrimethylcyclohexanoneHCID 76322Cyclohexanone, 3,3-dimethyl-

Product 1

HCID 33665(1,1'-Biphenyl)-2,3'-diol

Procedure

Following the same procedure as in Example A.2 3 mol of 3,3-dimethylcyclohexanone are used instead of 3 mol of dihydroisophorone. The product had a melting point of 190°-201° C.

Sources & evidence

ORD record
ord-8bf209e73fb84761a10ac0ffc92fdaea
Source dataset
uspto-grants-1993_07
Patent number
US05227458

Reaction notes

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