2-Methyl-4-nitroaniline → HCID 70465507, compound

HRID 484789Notes

Reaction equation

HRID 484789 reaction equation
[Cl:1][C:2]1[CH2:7][CH2:6][CH2:5][CH2:4][N:3]=1.[CH3:8][C:9]1[CH:15]=[C:14]([N+:16]([O-])=O)[CH:13]=[CH:12][C:10]=1[NH2:11]>>[ClH:1].[ClH:1].[CH3:8][C:9]1[CH:15]=[C:14]([NH2:16])[CH:13]=[CH:12][C:10]=1[NH:11][C:2]1[CH2:7][CH2:6][CH2:5][CH2:4][N:3]=1

Participants

3

Reactant 2

HCID 74412-Methyl-4-nitroanilineHCID 15111218HCID 15111218, compound

Product 1

HCID 70465507HCID 70465507, compoundYield 59.4%

Procedure

The title compound (8.2 g) was prepared by the methods of Examples 8 and 9 using 2-chloroazacyclohex-1-ene (0.10 mole), prepared as in Example 2, and 7.6 g (0.05 mole) of 2-methyl-4-nitroaniline. Structure assignment was supported by the nmr spectrum and by elemental analysis.

Sources & evidence

ORD record
ord-5c69d9dc76ee43ce9fd6ec3f9eaf3436
Source dataset
uspto-grants-1985_08
Patent number
US04533739

Reaction notes

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