HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Dioxide → Ethyl 2-bromo-3-phenylpropanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Dioxide | HCID 280 | — |
| Reactant | Ethyl bromo-(phenylmethyl)propanedioate | HCID 86007639 | — |
| Product | Ethyl 2-bromo-3-phenylpropanoate | HCID 4737529 | — |
Reaction Steps
Ethyl bromo-(phenylmethyl)propandioate (XXVI, Example 60, 130 g.) is heated under reduced pressure to 140° with vigorous evolution of carbon dioxide. When decarboxylation is complete (about 5 minutes), the mixture is distilled to give ethyl 2-bromo-3-phenylpropionate, b.p. 120°/30 mm.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04534897 |
| Source dataset | uspto-grants-1985_08 |
| ORD ID | ord-105355d6d3dc4bf48e8128d58f3d322d |
| Source note | uspto-grants-1985_08 |