HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Iodide → Methyl 2-(2-methyl-4-benzofuranyloxymethyl)benzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Iodide | HCID 5238 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Methyl 2-(bromomethyl)benzoate | HCID 2734813 | — |
| Reactant | 4-Hydroxy-2-methylbenzofuran | HCID 12174561 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Methyl 2-(2-methyl-4-benzofuranyloxymethyl)benzoate | HCID 20271537 | — |
Reaction Steps
4-Hydroxy-2-methylbenzofuran (2/3 g, 14.4 M), methyl 2-bromomethylbenzoate (3.29 g, 14.4 mM), anhydrous potassium carbonate (2.135 g), sodium iodide (87 mg) and methanol (20 ml) were reacted together in an analogous manner to that described in Example 5(A) to give methyl 2-(2-methyl-4-benzofuranyloxymethyl)benzoate, m.p. 93°-95° C. (Found: C, 72.74; H, 5.26. C18H16O4 required C, 72.96; H, 5.44%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04535183 |
| Source dataset | uspto-grants-1985_08 |
| ORD ID | ord-23dae454284c40999ba7325741f314c3 |
| Source note | uspto-grants-1985_08 |