Phosphorus sulfide (P2S5) → HCID 70478398, compound

HRID 485237Notes

Reaction equation

HRID 485237 reaction equation
[CH2:1]([P:3]([CH2:8][O:9][C:10]1[CH:15]=[C:14]([O:16][C:17]2[CH:22]=[CH:21][C:20]([C:23]([F:26])([F:25])[F:24])=[CH:19][C:18]=2[Cl:27])[CH:13]=[CH:12][C:11]=1[N+:28]([O-:30])=[O:29])(=O)[O:4][CH2:5][CH3:6])[CH3:2].P12(SP3(SP(SP(S3)(S1)=S)(=S)S2)=S)=[S:32]>>[CH2:1]([P:3]([CH2:8][O:9][C:10]1[CH:15]=[C:14]([O:16][C:17]2[CH:22]=[CH:21][C:20]([C:23]([F:26])([F:25])[F:24])=[CH:19][C:18]=2[Cl:27])[CH:13]=[CH:12][C:11]=1[N+:28]([O-:30])=[O:29])(=[S:32])[O:4][CH2:5][CH3:6])[CH3:2]

Participants

3

Reactant 2

HCID 14817Phosphorus sulfide (P2S5)HCID 70478362HCID 70478362, compound

Product 1

HCID 70478398HCID 70478398, compound

Procedure

A mixture of ethyl P-ethyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenoxymethylphosphinate (4.7 mmol) and phosphorus pentasulfide (1.2 mmol) is heated to 150°-160° under nitrogen for 3-4 hours. After cooling, the residue is purified by prep. TLC to give O-ethyl P-ethyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenoxymethylphosphinothioate.

Workup

  1. temperatureis heated to 150°-160° under nitrogen for 3-4 hours
  2. temperatureAfter cooling
  3. customthe residue is purified by prep

Sources & evidence

ORD record
ord-aefb75db061a4ddf93415a4c0bd057e2
Source dataset
uspto-grants-1985_08
Patent number
US04536355

Reaction notes

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