HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trimethyl phosphite → Hosphinecarboxylic acid, dimethoxy-, 3,4-dichlorophenyl ester, oxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trimethyl phosphite | HCID 8472 | — |
| Reactant | 3,4-Dichlorophenyl carbonochloridate | HCID 13077890 | — |
| Product | Hosphinecarboxylic acid, dimethoxy-, 3,4-dichlorophenyl ester, oxide | HCID 512117 | — |
Reaction Steps
From 10.3 g (85 mmole) of trimethylphosphite and 13.5 g (60 mmole) of 3,4-dichlorophenyl chloroformate (100°, 2 hours). Yield 11.4 g (64%) B.p.0.04 154° C. nD20 1.5271. Solidifies to colourless crystals m.p. 58°-9° C. Analysis for C9H9Cl2O5P. Found (calculated): C 36.06 (36.14), H 3.31 (3.03), Cl 23.58 (23.71), P 10.50 (10.36). NMR (CDCl3)δ: 3.93 and 4.07 (CH3O), 7.0-7.6 (C6H3) IR (KBr)cm-1 : 1740 (CO), 1205, 1200, 1105, 1055, 1020.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04536400 |
| Source dataset | uspto-grants-1985_08 |
| ORD ID | ord-2b44d81425ff481e93f4314ed81816d7 |
| Source note | uspto-grants-1985_08 |