HCID 9795017, compound → Dibenzo(b,f)thiepin

HRID 485459Notes

Reaction equation

HRID 485459 reaction equation
[CH:1]1[C:11]2[CH2:10][CH2:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6][C:5]=2[CH:4]=[C:3](C(O)=O)[CH:2]=1.C1C2C=CC3C=CC=CC=3SC=2C=C(C(O)=O)C=1>>[CH:1]1[C:11]2[CH:10]=[CH:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 9795017HCID 9795017, compoundHCID 13151858HCID 13151858, compound

Product 1

HCID 136074Dibenzo(b,f)thiepin

Procedure

In a similar manner, substituting 10,11-dihydrodibenzo[b,f]thiepin-3-carboxylic acid or dibenzo[b,f]thiepin-3-carboxylic acid for the carboxylic acid starting material employed in Step 1, there is obtained the corresponding 10,11-dihydrobibenzo[b,f]thiepin-3-(4-hydroxy-Δ3 -pyrrolin-3-yl-2,5-dione) or dibenzo[b,f]thiepin-3-(4-hydroxy-Δ3 -pyrrolin-3-yl-2,5-dione).

Sources & evidence

ORD record
ord-e084db0d63a34b53b502b33de6c15b23
Source dataset
uspto-grants-1985_08
Patent number
US04536507

Reaction notes

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