HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formic Acid → HCID 20270219, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formic Acid | HCID 284 | — |
| Reactant | HCID 13151854 | HCID 13151854 | — |
| Catalyst | Nickel | HCID 935 | — |
| Product | HCID 20270219 | HCID 20270219 | — |
Reaction Steps
Heat a mixture of 5.0 gm. of 3-cyano-10,11-dihydro-11-oxodibenzo[b,f]thiepin and 4.0 gm. of Raney nickel alloy in 60 ml. of 75% (v/v) aqueous formic acid at reflux for 1.5 hours. Cool to room temperature and filter. Concentrate to small volume and extract with methylene chloride. Wash the extract with water and with 1N sodium bicarbonate until neutral. Dry the neutral extract over sodium sulfate and concentrate to dryness to obtain the title product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04536507 |
| Source dataset | uspto-grants-1985_08 |
| ORD ID | ord-75b8480172b3466e8dd005a6e6b74e6f |
| Source note | uspto-grants-1985_08 |