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HRID485735

反应详情

EQUATION

反应方程式

HRID 485735 的结构方程式

REACTANTS

反应物

2
结构：O=c1c(O)c(O)c1=O
HCID17913

Squaric acid

C4H2O4

结构：CC1(C)CC(NCCO)CC(C)(C)N1
HCID10703227

Ethanol, 2-[(2,2,6,6-tetramethyl-4-piperidinyl)amino]-

C11H24N2O

PRODUCTS

生成物

1
结构：CC1(C)CC(N(CCO)c2c([O-])[c+](N(CCO)C3CC(C)(C)NC(C)(C)C3)[c+]2[O-])CC(C)(C)N1
HCID178426473

未命名化合物

收率 66.8%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(C)=O
溶剂HCID180

Acetone

C3H6O

PROCEDURE

实验过程

5.7 g of quadratic acid (0.05 mole) and 50.1 g of 97.7% strength 4-(2-hydroxyethyl)amino-2,2,6,6-tetramethylpiperidine (0.244 mole) were heated for five hours to 200° C. After cooling, the reaction product was boiled with 150 cc of acetone and, after another cooling step, vacuum-filtered and washed with acetone, thus obtaining 16.0 g. Yield: 66.8% of theory, mp 309°-311° C. Extinction (g/l.cm) at 336 nm: 97.

WORKUP

后处理

  1. temperatureAfter cooling
  2. filtrationafter another cooling step, vacuum-filtered
  3. washwashed with acetone
  4. customthus obtaining 16.0 g