1,3-Dinitrobenzene → HCID 13466713, compound

HRID 485951Notes

Reaction equation

HRID 485951 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-:12])=[O:11])[CH:5]=1)([O-:3])=[O:2].[C:13]([C:17]1[CH:22]=[CH:21][CH:20]=[C:19]([C:23]([CH3:26])([CH3:25])[CH3:24])[C:18]=1[OH:27])([CH3:16])([CH3:15])[CH3:14]>>[C:23]([C:19]1[CH:20]=[C:21]([C:7]2[CH:8]=[CH:9][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][C:6]=2[N+:10]([O-:12])=[O:11])[CH:22]=[C:17]([C:13]([CH3:16])([CH3:15])[CH3:14])[C:18]=1[OH:27])([CH3:26])([CH3:25])[CH3:24]

Participants

3

Reactant 2

HCID 74521,3-DinitrobenzeneHCID 314052,6-Di-tert-butylphenol

Product 1

HCID 13466713HCID 13466713, compoundYield 61.5%

Procedure

Example I was repeated except that 122 mg (0.73 mmol) of 1,3-dinitrobenzene and 100 mg (0.48 mmol) of 2,6-di-t-butylphenol were used, and the reaction was conducted for two hours. The process afforded 110 mg (61% yield) of crystalline 2,6-di-t-butyl-4-(2',4'-dinitrophenyl)phenol.

Sources & evidence

ORD record
ord-733b76e67b3f4e8bbe242e20b12ab608
Source dataset
uspto-grants-1985_08
Patent number
US04538006

Reaction notes

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