Phosgene → HCID 18365510, compound

HRID 486754Notes

Reaction equation

HRID 486754 reaction equation
[CH:1]1[CH:6]=[CH:5][C:4]([NH:7][C:8]2[CH:13]=[CH:12][CH:11]=[C:10]([Cl:14])[CH:9]=2)=[CH:3][CH:2]=1.[C:15](Cl)([Cl:17])=[O:16]>C1(C)C=CC=CC=1>[Cl:14][C:10]1[CH:9]=[C:8]([N:7]([C:4]2[CH:3]=[CH:2][CH:1]=[CH:6][CH:5]=2)[C:15]([Cl:17])=[O:16])[CH:13]=[CH:12][CH:11]=1

Participants

4

Reactant 2

HCID 6371PhosgeneHCID 75453-Chlorodiphenylamine2×

Product 1

HCID 18365510HCID 18365510, compoundYield 58%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Following the procedure of Example 15, Step A, 20.4 g (100 mmole) of 3-chlorodiphenylamine i.e., N-(3-chlorophenyl)aniline] and phosgene in toluene gave 15.4 g (58%) of N-(3-chlorophenyl)-N-phenylcarbamoyl chloride.

Sources & evidence

ORD record
ord-919943d4e5364cc6827607af13e69fb1
Source dataset
uspto-grants-1994_03
Patent number
US05292726

Reaction notes

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