HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichloromethane → Methyl (2-chloro-2-oxoethoxy)acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 2,3-Dimethoxy-3-oxopropanoate | HCID 22999080 | — |
| Product | Methyl (2-chloro-2-oxoethoxy)acetate | HCID 12361282 | — |
Reaction Steps
Mono-methyl methoxymalonate (9.8 grams, 0.07 mole), prepared In Example LVI (Compound 214) was reacted with thionyl chloride (15.74 grams, 0.13 mole) in 100 milliliters of methylene chloride in a manner similar to that described in Example LIII Part C, to give 11.06 grams (0.07 mole) of methyl (chlorocarbonyl)methoxyacetate. NMR analysis of the product indicated the following:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05292937 |
| Source dataset | uspto-grants-1994_03 |
| ORD ID | ord-d1e11fa5eb374e43a5e034a94e54dbf9 |
| Source note | uspto-grants-1994_03 |