HuagongsheHuagongshe Chemistry Print Report · For research reference only
Malononitrile → 2-(1-Ethoxypropylidene)malononitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Malononitrile | HCID 8010 | — |
| Reactant | Ethyl orthopropionate | HCID 66995 | — |
| Product | 2-(1-Ethoxypropylidene)malononitrile | HCID 231470 | 93% |
Reaction Steps
Triethyl orthopropionate (1000 g, 5.5 mole) and malononitrile (363 g, 5.5 mole) were combined and refluxed for 5 hours. The reaction mixture was cooled to room temperature and the residue was distilled at 125°-143° C. (3-7 mm Hg) to afford 768.1 g (93%) of (1-ethoxypropylidene)malononitrile as an orange liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05294612 |
| Source dataset | uspto-grants-1994_03 |
| ORD ID | ord-dbb6f2cfa80a412cb5276334beaed1dc |
| Source note | uspto-grants-1994_03 |