huagongshe.com
HRID487656

反应详情

EQUATION

反应方程式

HRID 487656 的结构方程式

REACTANTS

反应物

2
结构：CC1(C)Oc2ccc(C#N)cc2[C@@H](n2ccc(CO[Si](C)(C)C(C)(C)C)cc2=O)[C@@H]1O
HCID131718356

未命名化合物

结构：CC1(C)Oc2ccc(C(F)(F)F)cc2[C@@H](n2ccc(CO[Si](C)(C)C(C)(C)C)cc2=O)[C@@H]1O
HCID131718360

未命名化合物

PRODUCTS

生成物

1
结构：CC1(C)C=C(n2ccc(CO[Si](C)(C)C(C)(C)C)cc2=O)c2cc(C(F)(F)F)ccc2O1
HCID21746926

未命名化合物

PROCEDURE

实验过程

The reaction and after treatment of Example 8 are repeated, except that the trans-3-hydroxy-6-cyano-3,4-dihydro-2,2-dimethyl-4-(1,2-dihydro-2-oxo-4-t-butyldimethylsilyloxymethyl-1-pyridinyl)-2H-benzo[b]pyran used in Example 8 is replaced with the trans-3-hydroxy-6-trifluoromethyl-3,4-dihydro-2,2-dimethyl-4-(1,2-dihydro-2-oxo-4-t-butyldimethylsilyloxymethyl-1-pyridinyl)-2H-benzo[b]pyran obtained in Example 50. Thus, 6-trifluoromethyl-2,2-dimethyl-4-(1,2-dihydro-2-oxo-4-t-butyldimethylsilyloxymethyl-1-pyridinyl)-2H-benzo[b]pyran is obtained.

WORKUP

后处理

  1. customThe reaction