Zinc Nitrate → CID 12069775

HRID 487711Notes

Reaction equation

HRID 487711 reaction equation
[N+]([O-])([O-])=O.[Zn+2:5].[N+]([O-])([O-])=O.[C:10]([O-:21])(=[O:20])[C:11]1[CH:19]=[CH:18][C:14]([C:15]([O-:17])=[O:16])=[CH:13][CH:12]=1.[Na+].[Na+]>O>[C:10]([O-:21])(=[O:20])[C:11]1[CH:19]=[CH:18][C:14]([C:15]([O-:17])=[O:16])=[CH:13][CH:12]=1.[Zn+2:5]

Participants

4

Reactant 2

HCID 24518Zinc Nitrate2×HCID 82305Disodium terephthalate2×

Product 1

HCID 12069775CID 12069775

Reagents, catalysts & solvents 1

HCID 962WaterSolvent4×

Procedure

Zinc terephthalate was prepared by slow addition of a dilute zinc nitrate solution to sodium terephthalate. The procedure was carried out by reacting 50 mmole of sodium terephthalate in 300 mls of deionized water (Solution A) with an equimolar amount of zinc nitrate in 300 mls of water (Solution B). The reaction was carried out at reflux with an addition time of at least one hour. The reaction mixture was then allowed to reflux for approximately one hour. At the end of this time it was allowed to cool to room temperature, filtered, washed with deionized water and dried in an air oven to produce anhydrous zinc terephthalate.

Workup

  1. temperatureat reflux with an addition time of at least one hour
  2. temperatureto reflux for approximately one hour
  3. filtrationfiltered
  4. washwashed with deionized water
  5. customdried in an air oven

Sources & evidence

ORD record
ord-020e47ffaa9742be8c4ecc0cd5d5684c
Source dataset
uspto-grants-1994_03
Patent number
US05296585

Reaction notes

Loading…