HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trichloromethylsilane → HCID 131718361, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trichloromethylsilane | HCID 6399 | — |
| Reactant | Neophyl chloride | HCID 68191 | — |
| Reactant | Magnesium | HCID 5462224 | — |
| Reactant | HCID 178418740 | HCID 178418740 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 131718361 | HCID 131718361 | 65% |
Reaction Steps
In accord with the procedure of Example 1, neophylmagnesium chloride was prepared from 674 g (4 mol) of neophyl chloride and 105 g (4.4 mol) of magnesium turnings in 1.5 liters of dry THF. The neophylmagnesium chloride was added to 598 g (4 mol) of methyltrichlorosilane and 2 g of cuprous cyanide in 500 ml of THF. 640 g (65% of theory) of neophylmethyldichlorosilane was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05296624 |
| Source dataset | uspto-grants-1994_03 |
| ORD ID | ord-c8ea5e0ccad847beb6efceb6b6122ccd |
| Source note | uspto-grants-1994_03 |