Ethanol, 2-amino-, 1-nitrate, nitrate (1:1) → HCID 18961043, compound

HRID 487952Notes

Reaction equation

HRID 487952 reaction equation
[N+]([O-])(O)=O.[N+:5]([O:8][CH2:9][CH2:10][NH2:11])([O-:7])=[O:6].[O:12]=[C:13]1[NH:17][CH:16]([C:18](O)=[O:19])[CH:15]([C:21]2[S:22][CH:23]=[CH:24][CH:25]=2)[S:14]1>>[N+:5]([O:8][CH2:9][CH2:10][NH:11][C:18]([CH:16]1[CH:15]([C:21]2[S:22][CH:23]=[CH:24][CH:25]=2)[S:14][C:13](=[O:12])[NH:17]1)=[O:19])([O-:7])=[O:6]

Participants

3

Reactant 2

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 18961041HCID 18961041, compound

Product 1

HCID 18961043HCID 18961043, compound

Procedure

A procedure similar to that described in Example 1 was repeated, but using 350 mg of N-(2-nitrooxyethyl)-amine nitrate and 400 mg of 2-oxo-5-(2-thienyl)thiazolidine-4-carboxylic acid, to obtain 260 mg of the title compound as colorless crystals, melting at 120°-122° C. (after recrystallization from ethanol).

Workup

  1. customto obtain
  2. custom260 mg of the title compound as colorless crystals, melting at 120°-122° C. (after recrystallization from ethanol)

Sources & evidence

ORD record
ord-7ce1083a64b04e0d92dc57b2c087cc1b
Source dataset
uspto-grants-1994_03
Patent number
US05298516

Reaction notes

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